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Asymmetric Synthesis In Organophosphorus Chemistry

Author: Oleg I. Kolodiazhnyi
Publisher: John Wiley & Sons
ISBN: 3527341501
Size: 45.30 MB
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Authored by one of the leading experts in the field, this is the only comprehensive overview of chiral organophosphorus compounds, from asymmetric synthesis to catalysis and pharmacological applications. As such, this unique reference covers the chemical background as well as spectroscopical analysis of phosphorus compounds, and thoroughly describes all the various synthetic strategies for these substances. Metal-, organo- and biocatalyzed reactions for the introduction of phosphorus are explained as are asymmetric oxidation and reduction methods for the preparation of all possible oxidation states of phosphorus. The text also includes industrial applications for these compounds. Of particular interest to chemists working in the field of asymmetric synthesis, as well as to the pharmaceutical industry due to the increasing number of phosphorous-containing drugs.

Organophosphorus Chemistry

Author: Viktor Iaroshenko
Publisher: Wiley-VCH
ISBN: 3527335722
Size: 78.69 MB
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Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.

Organophosphorus Chemistry

Author: D. W. Allen
Publisher: Royal Society of Chemistry
ISBN: 1847550584
Size: 37.17 MB
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Organophoshorus Chemistry provides a comprehensive and critical review of the recent literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa- coordinated compounds, tervalent phosphorus acid derivatives, quiquevalent phosphorus acids, nucleotides and nucleic aicds, ylides and related compounds, phosphazenes and the application of physical methods in the study of organophosphorus compounds. This Specialist Periodical Report will be of value to research workers in universities, government and industrial research organisations whose work involves the use of organophosphorus compounds. It provides a concise but comprehensive survey of a vast field of study, with a wide variety of applications, enabling the reader to keep abreast of the latest developments in their specialist fields.

Phosphorus Iii Ligands In Homogeneous Catalysis

Author: Paul C. J. Kamer
Publisher: John Wiley & Sons
ISBN: 1118299701
Size: 51.38 MB
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Over the last 60 years the increasing knowledge of transition metalchemistry has resulted in an enormous advance of homogeneouscatalysis as an essential tool in both academic and industrialfields. Remarkably, phosphorus(III) donor ligands have played animportant role in several of the acknowledged catalytic reactions.The positive effects of phosphine ligands in transition metalhomogeneous catalysis have contributed largely to the evolution ofthe field into an indispensable tool in organic synthesis and theindustrial production of chemicals. This book aims to address the design and synthesis of acomprehensive compilation of P(III) ligands for homogeneouscatalysis. It not only focuses on the well-known traditionalligands that have been explored by catalysis researchers, but alsoincludes promising ligand types that have traditionally beenignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysisand rational catalyst design, P-stereogenic ligands, calixarenes,supramolecular approaches, solid phase synthesis, biologicalapproaches, and solubility and separation. Ligand families covered in this book include phosphine,diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite,phosphinite, phosphole, phosphinine, phosphinidenene,phosphaalkenes, phosphaalkynes, P-chiral ligands, and cageligands. Each ligand class is accompanied by detailed and reliablesynthetic procedures. Often the rate limiting step in theapplication of ligands in catalysis is the synthesis of the ligandsthemselves, which can often be very challenging and time consuming.This book will provide helpful advice as to the accessibility ofligands as well as their synthesis, thereby allowing researchers tomake a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design andSynthesis is an essential overview of this important class ofcatalysts for academic and industrial researchers working incatalyst development, organometallic and synthetic chemistry.