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Handbook Of Bond Dissociation Energies In Organic Compounds

Author: Yu-Ran Luo
Publisher: CRC Press
ISBN: 1420039865
Size: 53.63 MB
Format: PDF, Kindle
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So many compounds, so many experiments reported by so many researchers using so many methods...Finding reliable data on bond dissociation energies (BDEs) can be like looking for a needle in a haystack. But these data are crucial to work in chemical kinetics, free radical chemistry, organic thermochemistry, and physical organic chemistry-so where does one turn? With data on almost 2900 bonds in 2500 organic compounds, the Handbook of Bond Dissociation Energies in Organic Compounds is the first comprehensive collection of experimental BDE data. Author Dr. Yu-Ran Luo has spent more than 10 years collecting, assessing, and tabulating BDE experiment results and presents them here in a well-organized, easy-to-use series of tables. For each compound, the tables list up to five recent experimental values, indicate which is the recommended value, give the method used to determine each value, and provide references for each value. An outstanding format and complete indexing both by compound name and by compound class make searching for data quick and easy. While experimental BDE values carry inherent uncertainties, the value of this compilation does not. There is simply no other resource that provides as much data. With this book, when you need data on a particular bond dissociation energy, you'll find it within just a few minutes.

Comprehensive Handbook Of Chemical Bond Energies

Author: Yu-Ran Luo
Publisher: CRC Press
ISBN: 9781420007282
Size: 29.54 MB
Format: PDF, Mobi
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Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials, bioengineering, environmental chemistry, and space science. Reflecting the frequent additions and updates of bond dissociation energy (BDE) data throughout the literature, the Comprehensive Handbook of Chemical Bond Energies compiles the most recent experimental BDE data for more than 19,600 bonds of 102 elements. The author organizes the data by bond type, functional group, bond order, bond degree, molecular size, and structure for ease of use. Data can also be located using the Periodic table. The book presents data for organic molecules, biochemicals, and radicals as well as clusters, ions, hydrogen- and surface-bonded species, van der Waals complexes, isotopic species, and halogen-clusters/complexes. It also introduces entirely new data for inorganics and organometallics. The final chapter summarizes the heats of formation for atoms, inorganic/organic radicals, and monoatomic ions in the gas phase. The Comprehensive Handbook of Chemical Bond Energies offers quick access to experimental BDE data in the most inclusive, well-organized, and up-to-date collection available today.

Handbook Of Antioxidants

Author: Evgeny T. Denisov
Publisher: CRC Press
ISBN: 9780849390043
Size: 49.48 MB
Format: PDF, Mobi
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Designed for scientists and engineers involved in the chemistry and technology of antioxidants, the Second Edition of this popular handbook continues to provide comprehensive data on the thermodynamics and reactivity of antioxidants. Fully revised and updated, the Second Edition provides the latest data on antioxidants and polymer stabilizers, new data for biological antioxidants, a corrected list of bond dissociation energies, and a full bibliography. Additions and changes in the New Edition: The latest data on O-H bond dissociation energies of phenols and the new scale these values Thermodynamic functions of antioxidants and their intermediate presented in tables A table with current data on dissociation energies of C-H bonds of hydrocarbons and oxygen-containing compounds Rate constants and activation energies of reactions of antioxidants with ozone, nitrogen dioxide, and hydroperoxide Kinetic characteristics of benzoquinine reactions with antioxidants Rate constants of free radical generation through biomolecular reactions with ozone, nitrogen dioxide, and hydroperoxide All calculated data from the first edition has been recalculated in accordance with new data on dissociation energies and parameters of reactivity Data on thermodynamics of hydrogen bond formation of antioxidants All data on cyclic mechanisms of chain termination by antioxidants collected into a special chapter Special chapters on bioantioxidants and stabilization of polymers The Handbook of Antioxidants puts essential data at your fingertips. Its comprehensive nature and ease-of-use make it the resource for scientific researchers and engineers working in the field of physical chemistry of antioxidants.

Organosilicon Compounds Two Volume Set

Author: Vladimir Ya Lee
Publisher: Academic Press
ISBN: 0128143630
Size: 29.43 MB
Format: PDF
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Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects Covers important breakthroughs in the field, along with historically significant achievements Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more

Organosilicon Compounds

Author: Vladimir Ya Lee
Publisher: Academic Press
ISBN: 0128019913
Size: 35.11 MB
Format: PDF
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Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Massenspektrometrie

Author: Jürgen H Gross
Publisher: Springer-Verlag
ISBN: 3827429811
Size: 19.25 MB
Format: PDF, Docs
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Mit Massenspektrometrie – ein Lehrbuch liegt ein Werk vor, das mit seiner umfassenden, präzisen Darstellung sowie seinen vielen gelungenen Illustrationen und Fotos eine Lücke auf dem deutschsprachigen Markt schließt. Dieses im englischsprachigen Raum bereits gut etablierte Buch führt auf grundlegende Weise an die Massenspektrometrie heran, indem es die Prinzipien, Methoden und Anwendungen logisch aufeinander aufbauend erklärt. Schritt für Schritt lernt der Leser, was diese analytische Methode leisten kann, auf welch vielfältige Art Massenspektrometer isolierte Ionen in der Gasphase erzeugen, selektieren und manipulieren können und wie man aus den resultierenden Massenspektren analytische Information gewinnt. Moderne sanfte Ionisationsmethoden wie ESI, APCI oder MALDI, klassische Verfahren wie EI, CI, FAB oder FD, Oberflächentechniken wie DESI oder DART und elementmassenspektrometrische Verfahren werden didaktisch durchdacht behandelt. Studienanfänger werden von dem Werk ebenso profitieren wie Fortgeschrittene und Praktiker. Ergänzend zum Buch betreibt der Autor eine frei zugängliche (englischsprachige) Internetseite mit zahlreichen Übungsaufgaben, Lösungen und Bonus-Material unter http://www.ms-textbook.com

Crc Handbook Of Chemistry And Physics

Author: Chemical Rubber Company
Publisher:
ISBN:
Size: 30.86 MB
Format: PDF, Kindle
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Continues to be the most accurate, reliable and current resource available on data needed by chemists, physicists and engineers. It provides wide coverage of data on properties of inorganic and organic compounds. Some of the most heavily used tables were recently updated and expanded including: Physical Properties of Inorganic Compounds; Enthalpy of Fusion; Bond Dissociation Energies; Table of the Isotopes; Inorganic Ion and Ligand Nomenclature; Chemical Carcinogens; and Global Temperature Trends for the past 150 years.

Crc Handbook Of Chemistry And Physics 88th Edition

Author: David R. Lide
Publisher: CRC Press
ISBN: 9780849304880
Size: 41.34 MB
Format: PDF, Kindle
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The CRC Handbook of Chemistry and Physics, 88th Edition continues to offer the most authoritative, up-to-date data to scientists around the world. This edition contains NEW tables on Properties of Ionic Liquids, Solubilities of Hydrocarbons in Sea Water, Solubility of Organic Compounds in Superheated Water, and Nutritive Value of Foods. It also updates many tables including Critical Constants, Heats of Vaporization, Aqueous Solubility of Organic Compounds, Vapor Pressure of Mercury, Scientific Abbreviations and Symbols, and Bond Dissociation Energies. The 88th Edition also presents a new Foreword written by Dr. Harold Kroto, a 1996 Nobel Laureate in Chemistry.

Crc Handbook Of Chemistry And Physics 94th Edition

Author: William M. Haynes
Publisher: CRC Press
ISBN: 1466571152
Size: 77.83 MB
Format: PDF, Mobi
View: 7426
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Celebrating the 100th anniversary of the CRC Handbook of Chemistry and Physics, this 94th edition is an update of a classic reference, mirroring the growth and direction of science for a century. The Handbook continues to be the most accessed and respected scientific reference in the science, technical, and medical communities. An authoritative resource consisting of tables of data, its usefulness spans every discipline. Originally a 116-page pocket-sized book, known as the Rubber Handbook, the CRC Handbook of Chemistry and Physics comprises 2,600 pages of critically evaluated data. An essential resource for scientists around the world, the Handbook is now available in print, eBook, and online formats. New tables: Section 7: Biochemistry Properties of Fatty Acid Methyl and Ethyl Esters Related to Biofuels Section 8: Analytical Chemistry Gas Chromatographic Retention Indices Detectors for Liquid Chromatography Organic Analytical Reagents for the Determination of Inorganic Ions Section 12: Properties of Solids Properties of Selected Materials at Cryogenic Temperatures Significantly updated and expanded tables: Section 3: Physical Constants of Organic Compounds Expansion of Diamagnetic Susceptibility of Selected Organic Compounds Section 5: Thermochemistry, Electrochemistry, and Solution Chemistry Update of Electrochemical Series Section 6: Fluid Properties Expansion of Thermophysical Properties of Selected Fluids at Saturation Major expansion and update of Viscosity of Liquid Metals Section 7: Biochemistry Update of Properties of Fatty Acids and Their Methyl Esters Section 8: Analytical Chemistry Major expansion of Abbreviations and Symbols Used in Analytical Chemistry Section 9: Molecular Structure and Spectroscopy Update of Bond Dissociation Energies Section 11: Nuclear and Particle Physics Update of Summary Tables of Particle Properties Section 14: Geophysics, Astronomy, and Acoustics Update of Atmospheric Concentration of Carbon Dioxide, 1958-2012 Update of Global Temperature Trend, 1880-2012 Major update of Speed of Sound in Various Media Section 15: Practical Laboratory Data Update of Laboratory Solvents and Other Liquid Reagents Major update of Density of Solvents as a Function of Temperature Major update of Dependence of Boiling Point on Pressure Section 16: Health and Safety Information Major update of Threshold Limits for Airborne Contaminants Appendix A: Major update of Mathematical Tables Appendix B: Update of Sources of Physical and Chemical Data