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Homogeneous Catalysis For Unreactive Bond Activation

Author: Zhang-Jie Shi
Publisher: John Wiley & Sons
ISBN: 1118788990
Size: 33.31 MB
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This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters covers key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon. The first part of the book discusses homogeneous catalysis in the activation and transformation of C-Cl and C-F, highlighting their basic activation modes, cross-coupling, and intensive mechanisms. The second part of the book focuses on C-N, C-S, and C-O bonds, mentioning their catalytic pathways. Finally, C-H and C-C bonds, their activation, chemical transformations, and applicability are covered. Overall, the book presents methodologies that can be applied to the efficient synthesis of drug molecules and fine chemicals. Through their presentation, the authors show that synthetic chemistry can be done in greener ways that limit hazards and pollution.

Activation Of Unreactive Bonds And Organic Synthesis

Author: Shinji Murai
Publisher: Springer
ISBN: 3540685251
Size: 34.14 MB
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In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

Advances In Organometallic Chemistry

Author: Pedro J. Pérez
Publisher: Academic Press
ISBN: 0128155108
Size: 79.63 MB
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Advances in Organometallic Chemistry, Volume 70, contains authoritative review articles of worldwide known researchers in the field of organometallic chemistry. This longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Topics of note in this new release include Carbon Dioxide Electroreduction Catalyzed by Organometallic Complexes, Single-electron Elementary Steps in Homogeneous Organometallic Catalysis, Recent advances in catalytic hydrosilylation of carbonyl groups mediated by well-defined first-row late transition metals, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Activating Unreactive Substrates

Author: Carsten Bolm
Publisher: John Wiley & Sons
ISBN: 3527318232
Size: 26.55 MB
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The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.

Theoretical Aspects Of Homogeneous Catalysis

Author: Piet W.N.M. van Leeuwen
Publisher: Springer Science & Business Media
ISBN: 9780792331070
Size: 71.32 MB
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This publication is the first to present the quantitative application of quantum chemistry to organometallic reactions. Great progress has been made in recent years in the calculation of transition states of organometallic conversions in both homo and heterogeneous catalysis. This volume, which contains seven contributions by leading scientists, deals with key reactions of homogeneous catalysis including oxidative addition, migratory insertions, 2+2 additions, the Wacker reaction, and epoxidation. The book provides experimental chemists with an up-to-date overview of the state of the art in this field, and will stimulate an adjustment of views previously based on semiempirical calculations. For researchers and advanced graduate students whose work involves organometallics and catalysis.

Catalytic Activation And Functionalisation Of Light Alkanes

Author: E.G. Derouane
Publisher: Springer Science & Business Media
ISBN: 9780792349600
Size: 37.12 MB
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Light alkanes tend to be resistant to many forms of activation. The horizontal approach of the present book covers homogeneous, heterogeneous and biological catalysis, thus allowing readers to gain an awareness of progress and ideas in research areas different from their own. The book contains both general chapters, giving an overview of the subject, and specialised contributions that deal with the details and state of the art. A specialist report is also included which gives a critical insight into current progress and discusses future prospects and major challenges. Audience: Newcomers and senior researchers in the field of alkane activation. The mixed theoretical and practical approach will be of interest to researchers and industrialists alike.

Dioxygen Activation And Homogeneous Catalytic Oxidation

Author: L. I. Simándi
Publisher: Elsevier Science Ltd
ISBN: 9780444888761
Size: 44.97 MB
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Dioxygen activation is a rapidly developing field in which research is directed at (1) modelling of biological oxidations, (2) design and utilization of new catalysts for oxidative transformations of organic substrates, (3) application of O 2 (and H 2 O 2 ) as a cheap oxidant in the manufacture of fine and bulk chemicals. Provided here is a collection of both review and original papers covering all aspects of dioxygen activation. All papers provide background information of previous work. Reactions mechanisms are extensively treated and a keyword index facilitates quick orientation. The book should prove invaluable to organic, bioinorganic and coordination chemists as well as biochemists interested in homogeneous catalysis.

Applied Homogeneous Catalysis With Organometallic Compounds

Author: Boy Cornils
Publisher: Wiley-VCH
Size: 25.92 MB
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Homogeneous catalysis is the success story of organometallic chemistry. Since the discovery of hydroformylation by O. Roelen in 1938, catalytic applications have paved the way of organometallic compounds in industry. Bulk and fine chemicals, and even natural products are being produced via homogeneous organometallic catalysis. The enormous breadth of this topic in view of both basic research and industrial application is met in this three volume handbook edited jointly by W. A. Herrmann and B. Cornils. The list of contributors reads like a who-is-who in organometallic chemistry and homogeneous catalysis. In this handbook, experts will find the current state-of-the-art in their field and advanced students will benefit from the concise treatment of important catalytic reactions and processes. With its balanced presentation of the truly interdisciplinary topic and its outstanding editor- and authorship, the 'Cornils/Herrmann' is beyond common standards. Now in its second, completely revised and enlarged edition!


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Consists of reviews, condensations, and commentaries.