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Stereoselective Organocatalysis

Author: Ramon Rios Torres
Publisher: John Wiley & Sons
ISBN: 1118604709
Size: 34.82 MB
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Sets forth an important group of environmentally friendlyorganic reactions With contributions from leading international experts in organicsynthesis, this book presents all the most important methodologiesfor stereoselective organocatalysis, fully examining both theactivation mode as well as the type of bond formed. Clearexplanations guide researchers through all the most importantmethods used to form key chemical bonds, including carbon-carbon(C–C), carbon-nitrogen (C–N), and carbon-halogen(C–X) bonds. Moreover, readers will discover how the use ofnon-metallic catalysts facilitates a broad range of importantreactions that are environmentally friendly and fully meet thestandards of green chemistry. Stereoselective Organocatalysis begins with an historicaloverview and a review of activation modes in asymmetricorganocatalysis. The next group of chapters is organized by bondtype, making it easy to find bonds according to their applications.The first of these chapters takes a detailed look at the manyroutes to C–C bond formation. Next, the book covers: Organocatalytic C–N bond formation C–O bond formation C–X bond formation C–S, C–Se, and C–B bond formation Enantioselective organocatalytic reductions Cascade reactions forming both C–C bonds andC–heteroatom bonds The final chapter is devoted to the use of organocatalysis forthe synthesis of natural products. All the chapters in the book areextensively referenced, serving as a gateway to the growing body oforiginal research reports and reviews in the field. Based on the most recent findings and practices in organicsynthesis, Stereoselective Organocatalysis equips syntheticchemists with a group of organocatalytic reactions that will helpthem design green reactions and overcome many challenges in organicsynthesis.

Comprehensive Organic Synthesis

Publisher: Newnes
ISBN: 008097743X
Size: 53.12 MB
Format: PDF
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The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Science Of Synthesis Houben Weyl Methods Of Molecular Transformations Vol 7

Publisher: Georg Thieme Verlag
ISBN: 3131779616
Size: 67.35 MB
Format: PDF, Kindle
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Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab. // The content of this e-book was originally published in July 2004.

Comprehensive Organic Functional Group Transformations

Author: Alan R. Katritzky
Publisher: Elsevier
ISBN: 9780080423227
Size: 42.19 MB
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This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.

The Mizoroki Heck Reaction

Author: Martin Oestreich
Publisher: John Wiley & Sons
ISBN: 9780470716069
Size: 32.68 MB
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Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)

Hydrocarbon Chemistry

Author: George Andrew Olah
Publisher: Wiley-Interscience
Size: 39.35 MB
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Chemists today are under the gun to find solutions to a host of tough new challenges, including diminishing oil reserves, an array of environmental hazards, and ever more stringent government regulations. Now this book helps meet these challenges by bringing together, for the first time in one volume, all major aspects of contemporary hydrocarbon chemistry. Hydrocarbon Chemistry functions equally well as a working professional reference and an advanced-level student text. Each of its twelve chapters treats a specific type of hydrocarbon transformation and reviews, in depth, all related basic chemistry-including reactivity, selectivity, stereochemistry, and numerous mechanistic aspects-as well as a wide range of practical applications. Offers comprehensive coverage of the chemistry of alkanes, cycloalkanes, alkenes and dienes, acetylenes, and aromatics Includes developments in the field through early 1994 Treats all important aspects of the chemistry involved in hydrocarbon transformations Emphasizes the chemistry of processes used in the petrochemical industry, including cracking, reforming, isomerization, and alkylation Reviews, in detail, derivation reactions to form carbon heteroatom bonds as well as both traditional and recent hydrocarbon oxidation techniques Numerous formulas and flowsheets help illuminate all important concepts and practical processes discussed Destined to be the definitive work on the subject well into the twenty-first century, Hydrocarbon Chemistry is an indispensable resource for chemical and petroleum engineers; industrial researchers in organic, physical organic, and inorganic chemistry; and students of those and other related disciplines.