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Comprehensive Chemical Kinetics

Author: Nicholas Green
Publisher: Elsevier
ISBN: 9780080543444
Size: 46.43 MB
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Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade. This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances. . Presents considerable advances in the field made during the last decade. . Treats both the statistical as well as the fully quantum mechanical view.

The Theory Of Kinetics

Author: R.G. Compton
Publisher: Elsevier
ISBN: 0444600701
Size: 69.38 MB
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The Theory of Kinetics covers the practice and theory of kinetics and the kinetics of inorganic and organic reactions in gaseous and condensed phases and at interfaces. This text is composed of five chapters and starts with a review of the kinetic characterization of complex reaction systems. The succeeding chapter describes the formal and radical kinetics, as well as the energy factor in chain reactions. These topics are followed by a survey of the theory of the kinetics of elementary gas phase reactions and the unimolecular reaction of activated chemical species. The discussion then shifts to the general properties, reactions, and the theory of elementary reactions in solution. The last chapter examines the theory of kinetics of solid-state reactions. This book is of great value to physical, inorganic, and organic chemists.

Comprehensive Chemical Kinetics The Practice And Theory Of Kinetics V 1 3 Section 2 Homogeneous Decomposition And Isomerisation Reactions V 4 5 Section 3 Inorganic Reactions V 6 7 Section 4 Organic Reactions V 8 13 Section 5 Polymerisation Reactions V 14 15 Section 6 Oxidation And Combustion Reactions V 16 17 Section 7 Selected Elementary Reactions V 18 Section 8 Heterogeneous Reactions V 19 22 Section 10 Modern Methods Theory And Data V 24 41

Author: C. H. Bamford
Size: 38.66 MB
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Reactions In The Solid State

Author: Michael E. Brown
Publisher: Elsevier
ISBN: 9780080868165
Size: 15.62 MB
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The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

Applications Of Kinetic Modelling

Author: G. Hancock
Publisher: Elsevier
ISBN: 9780080527345
Size: 33.21 MB
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Volume 37 is concerned with the use and role of modelling in chemical kinetics and seeks to show the interplay of theory or simulation with experiment in a diversity of physico-chemical areas in which kinetics measurements provide significant physical insight. Areas of application covered within the volume include electro- and interfacial chemistry, physiology, biochemistry, solid state chemistry and chemical engineering. A leading contributor to this general area has been Professor W. John Albery, FRS, to whom the contributors and editors dedicate this book.

Modeling Of Chemical Reactions

Author: Robert W. Carr (Prof.)
Publisher: Elsevier Science Limited
ISBN: 9780444513663
Size: 54.10 MB
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Modeling of Chemical Reactions covers detailed chemical kinetics models for chemical reactions. Including a comprehensive treatment of pressure dependent reactions, which are frequently not incorporated into detailed chemical kinetic models, and the use of modern computational quantum chemistry, which has recently become an extraordinarily useful component of the reaction kinetics toolkit. It is intended both for those who need to model complex chemical reaction processes but have little background in the area, and those who are already have experience and would benefit from having a wide range of useful material gathered in one volume. The range of subject matter is wider than that found in many previous treatments of this subject. The technical level of the material is also quite wide, so that non-experts can gain a grasp of fundamentals, and experts also can find the book useful. * A solid introduction to kinetics * Material on computational quantum chemistry, an important new area for kinetics * Contains a chapter on construction of mechanisms, an approach only found in this book

Chemical Kinetics Fundamentals And Recent Developments

Author: Evgeny Denisov
Publisher: Elsevier
ISBN: 9780080529004
Size: 60.59 MB
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Comprehensive manual embracing essentially all the classical and modern areas of chemical kinetics. Provides details of modern applications in chemistry, technology and biochemistry. Special sections of the book treat subjects not covered sufficiently in other manuals, including: modern methods of experimental determination of rate constants of reactions including laser pico- and femtochemistry, magnetochemistry, and ESR; and descriptions of advanced theories of elementary chemical processes. - Comprehensive manual covering practically all areas of chemical kinetics, both classical and modern. - Adequate coverage given to topics not covered sufficiently by other works. - Covers fundamentals and recent developments in homogeneous catalysis and its modeling from a chemical kinetics perspective.