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Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9781891389047
Size: 27.31 MB
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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Author: Christoph Elschenbroich
Publisher: Springer-Verlag
ISBN: 3322993930
Size: 31.13 MB
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Ziel dieses Buches ist die Vermittlung gründlicher Kenntnisse der Organometallchemie der Haupt- und Nebengruppenelemente, etwa im zeitlichen Rahmen einer Vorlesung von vier Semesterwochenstunden. Hierbei kommen sowohl synthetische, strukturelle, spektroskopische, bindungstheoretische und mechanistische als auch anwendungsbezogene Aspekte zur Sprache. Gegenüber früheren Auflagen wurden neben zahlreichen Aktualisierungen vor allem die Organometallkatalyse und die Organometallchemie der f-Elemente verstärkt.

Author: Peter J. Harrington
Publisher: Wiley-Interscience
ISBN:
Size: 73.51 MB
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Examines the use of transition metal complexes as reagents for the synthesis of complex organic molecules. Presented here are total syntheses whose efficiency depends upon the unique reactivity patterns of organometallic complexes. For each total synthesis, the biological activity of the molecule is presented, followed by discussion of the principles of the organometallic processes involved.

Author: Jiro Tsuji
Publisher: John Wiley & Sons
ISBN: 9780471560272
Size: 66.68 MB
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Transition Metal Reagents and Catalysts Innovations in OrganicSynthesis Jiro Tsuji Emeritus Professor, Tokyo Institute ofTechnology, Japan Numerous innovative and practical syntheticmethods using transition metal complexes as either catalysts orreagents have been developed over the last 35 years. TransitionMetal Reagents and Catalysts combines the varied applications oftransition metal complexes in a unique and timely book in thisrapidly advancing area of organic synthesis. This text is an easilyunderstandable and enjoyable read for organic chemists who are notyet familiar with organo-transition metal chemistry. TransitionMetal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complexchemistry * An in-depth treatment of many innovative syntheticmethodologies * A rational classification of all reactions according tosubstrates and reaction mechanisms * Examples of important applications of transition metal catalysedreactions. A knowledge of organic synthesis using transition metal complexesis a must for all synthetic organic chemists. Written for chemistswho wish to apply novel synthetic methods using transition metalcomplexes to solve problems in organic and pharmaceuticalchemistry, such as synthesis of fine and bulk chemicals and naturalproducts, Transition Metal Reagents and Catalysts is an essentialreference source and an indispensible research companion.

Author: Peter E. Kündig
Publisher: Springer Science & Business Media
ISBN: 9783540016045
Size: 64.30 MB
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Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï⿬ by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students

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Publisher: Newnes
ISBN: 008097743X
Size: 79.41 MB
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The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Author: Dirk Steinborn
Publisher: John Wiley & Sons
ISBN: 3527327177
Size: 19.60 MB
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Catalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of everyday polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. Finally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis - homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis.

Author: Tsuneo Imamoto
Publisher: Georg Thieme Verlag
ISBN: 313177911X
Size: 10.27 MB
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Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab. // The content of this e-book was originally published in October 2002.

Author: Matthias Beller
Publisher: Springer Science & Business Media
ISBN: 3642390161
Size: 19.94 MB
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Transition Metal Catalyzed Carbonylation Reactions is a comprehensive monograph focusing on carbon monoxide usage. This book provides students and researchers in organic synthesis with a detailed discussion of carbonylation from the basics through to applications. The authors have structured the book around the types of reactions, based on the different nucleophiles involved. Scientists working in carbonylation or with carbon monoxide, as well as teachers of organic synthesis can use this book to become familiar with this important area of organic chemistry.

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Publisher: Elsevier
ISBN: 9780080532134
Size: 74.45 MB
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Almost all contemporary organic synthesis involve transition metal complexes as catalysts or particular reagents. The aim of this book is to provide the reader with detailed accounts of elementary processes within molecular catalysis to allow its development and as an aid in designing novel catalytic systems. The book comprises authoritative reviews on elementary processes from experts working at the forefront of organometallic chemistry. · This is the first book that focuses on elementary processes in transition metal complexes for understanding catalytic mechanisms · Provides detailed description of elementary processes involved in catalytic cycles by experts in the field · Provides an overview of the mechanisms of various homogeneous catalyses