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Transition Metals In The Synthesis Of Complex Organic Molecules

Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9781891389047
Size: 34.53 MB
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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Transition Metals In Total Synthesis

Author: Peter J. Harrington
Publisher: Wiley-Interscience
Size: 32.91 MB
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Examines the use of transition metal complexes as reagents for the synthesis of complex organic molecules. Presented here are total syntheses whose efficiency depends upon the unique reactivity patterns of organometallic complexes. For each total synthesis, the biological activity of the molecule is presented, followed by discussion of the principles of the organometallic processes involved.

Transition Metal Reagents And Catalysts

Author: Jiro Tsuji
Publisher: John Wiley & Sons
ISBN: 9780471560272
Size: 66.25 MB
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Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.

Fundamentals Of Organometallic Catalysis

Author: Dirk Steinborn
Publisher: John Wiley & Sons
ISBN: 3527327177
Size: 17.55 MB
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Catalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of everyday polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. Finally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis - homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis.

Science Of Synthesis Houben Weyl Methods Of Molecular Transformations Vol 2

Author: Tsuneo Imamoto
Publisher: Georg Thieme Verlag
ISBN: 313177911X
Size: 15.58 MB
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Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab. // The content of this e-book was originally published in October 2002.

Transition Metal Arene P Complexes In Organic Synthesis And Catalysis

Author: E.P. Kündig
Publisher: Springer Science & Business Media
ISBN: 9783540016045
Size: 60.34 MB
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Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï⿬ by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students

Organic Synthesis Using Transition Metals

Author: Roderick Bates
Publisher: John Wiley & Sons
ISBN: 1118313666
Size: 36.73 MB
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Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.


Author: Christoph Elschenbroich
Publisher: John Wiley & Sons
ISBN: 3527805168
Size: 19.95 MB
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THE textbook on organometallic chemistry. Comprehensive and up-to-date, the German original is already a classic, making this third completely revised and updated English edition a must for graduate students and lecturers in chemistry, inorganic chemists, chemists working with/on organometallics, bioinorganic chemists, complex chemists, and libraries. Over one third of the chapters have been expanded to incorporate developments since the previous editions, while the chapter on organometallic catalysis in synthesis and production appears for the first time in this form. From the reviews of the first English editions: 'The selection of material and the order of its presentation is first class ... Students and their instructors will find this book extraordinarily easy to use and extraordinarily useful.' -Chemistry in Britain 'Elschenbroich and Salzer have written the textbook of choice for graduate or senior-level courses that place an equal emphasis on main group element and transition metal organometallic chemistry. ... this book can be unequivocally recommended to any teacher or student of organometallic chemistry.' - Angewandte Chemie International Edition 'The breadth and depth of coverage are outstanding, and the excitement of synthetic organometallic chemistry comes across very strongly.' - Journal of the American Chemical Society

Transition Metal Catalyzed Carbonylation Reactions

Author: Matthias Beller
Publisher: Springer Science & Business Media
ISBN: 3642390161
Size: 17.13 MB
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Transition Metal Catalyzed Carbonylation Reactions is a comprehensive monograph focusing on carbon monoxide usage. This book provides students and researchers in organic synthesis with a detailed discussion of carbonylation from the basics through to applications. The authors have structured the book around the types of reactions, based on the different nucleophiles involved. Scientists working in carbonylation or with carbon monoxide, as well as teachers of organic synthesis can use this book to become familiar with this important area of organic chemistry.

Ruthenium In Organic Synthesis

Author: Shun-Ichi Murahashi
Publisher: John Wiley & Sons
ISBN: 3527605797
Size: 18.67 MB
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In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)