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Author: Galia Maayan
Publisher: John Wiley & Sons
ISBN: 1118517431
Size: 77.99 MB
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Metallofoldamers are oligomers that fold into three-dimensional structures in a controlled manner upon coordination with metal ions. Molecules in this class have shown an impressive ability to form single-handed helical structures and other three-dimensional architectures. Several metallofoldamers have been applied as sensors due to their selective folding when binding to a specific metal ion, while others show promise for applications as responsive materials on the basis of their ability to fold and unfold upon changes in the oxidation state of the coordinated metal ion, and as novel catalysts. Metallofoldamers: From Helicates to Biomimetic Architectures describes the variety of interactions between oligomers and metal species, with a focus on non-natural synthetic molecules. Topics covered include: the major classes of foldamers and their folding driving force metalloproteins and metalloenzymes helicates: self-assembly, structure and applications abiotic metallo-DNA metallo-PNA and iDNA metallopeptides interactions of biomimetic oligomers with metal ions applications of metallofoldamers

Comprehensive Supramolecular Chemistry Ii

Author: George W. Gokel
Publisher: Elsevier
ISBN: 0128031999
Size: 53.99 MB
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Comprehensive Supramolecular Chemistry II, Second Edition is a ‘one-stop shop’ that covers supramolecular chemistry, a field that originated from the work of researchers in organic, inorganic and physical chemistry, with some biological influence. The original edition was structured to reflect, in part, the origin of the field. However, in the past two decades, the field has changed a great deal as reflected in this new work that covers the general principles of supramolecular chemistry and molecular recognition, experimental and computational methods in supramolecular chemistry, supramolecular receptors, dynamic supramolecular chemistry, supramolecular engineering, crystallographic (engineered) assemblies, sensors, imaging agents, devices and the latest in nanotechnology. Each section begins with an introduction by an expert in the field, who offers an initial perspective on the development of the field. Each article begins with outlining basic concepts before moving on to more advanced material. Contains content that begins with the basics before moving on to more complex concepts, making it suitable for advanced undergraduates as well as academic researchers Focuses on application of the theory in practice, with particular focus on areas that have gained increasing importance in the 21st century, including nanomedicine, nanotechnology and medicinal chemistry Fully rewritten to make a completely up-to-date reference work that covers all the major advances that have taken place since the First Edition published in 1996

Chirality In Supramolecular Assemblies

Author: F. Richard Keene
Publisher: John Wiley & Sons
ISBN: 1118867319
Size: 48.52 MB
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Supramolecular chemistry deals with the organisation of molecules into defined assemblies using non-covalent interactions, including weaker and reversible interactions such as hydrogen bonds, and metal-ligand interactions. The aspect of stereochemistry within such chemical architectures, and in particular chirality, is of special interest as it impacts on considerations of molecular recognition, the development of functional materials, the vexed question of homochirality, nanoscale effects of interactions at interfaces, biocatalysis and enzymatic catalysis, and applications in organic synthesis. Chirality in Supramolecular Assemblies addresses many of these aspects, presenting a broad overview of this important and rapidly developing interdisciplinary field. Topics covered include: Origins of molecular and topological chirality Homochirogenesis Chirality in crystallinity Host-guest behavior Chiral influences in functional materials Chirality in network solids and coordination solids Aspects of chirality at interfaces Chirality in organic assemblies Chirality related to biocatalysis and enzymes in organic synthesis. This book is a valuable reference for researchers in the molecular sciences, materials science and biological science working with chiral supramolecular systems. It provides summaries and special insights by acknowledged international experts in the various fields.

Synergy In Supramolecular Chemistry

Author: Tatsuya Nabeshima
Publisher: CRC Press
ISBN: 1466595043
Size: 77.21 MB
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Cooperative and synergistic chemical events have attracted significant attention from many researchers engaged in organic chemistry, inorganic chemistry, biological chemistry, polymer chemistry, medicinal chemistry, and other related materials sciences. Synergistic supramolecular systems could be developed to amplify the functions and integration of molecular devices in ways that cannot be achieved by conventional single molecules. This book introduces basic concepts and examples of supramolecular chemistry in terms of cooperation and synergy, and it surveys recent progress in this field.

Bioorganometallic Chemistry

Author: Gérard Jaouen
Publisher: John Wiley & Sons
ISBN: 3527673458
Size: 18.16 MB
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An up-to-date reference reflecting the significant advances and important breakthroughs made in this emerging discipline over the last decade. As such, the book provides an overview of the latest developments and future trends in the field, focusing on such applications as the development of potentially active organometallic drugs against incurable diseases, as well as in such areas as catalysis, energy, analytical chemistry, and imaging. The renowned editor, who established the term "bioorganometallics", and his international team of experts have put together a valuable resource for researchers in organometallic, inorganic, medicinal, and biochemistry.

In Principio Erat Verbum

Author: Matthias Lutz-Bachmann
Publisher: Brepols Pub
Size: 20.30 MB
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Although metaphysics as a discipline can hardly be separated from Aristotle and his works, the questions it raises were certainly known to authors even before the reception of Aristotle in the thirteenth century. Even without the explicit use of this term the twelfth century manifested a strong interest in metaphysical questions under the guise of natural philosophy or divine science, leading M.-D. Chenu to coin the expression of a twelfth century eveil metaphysique. In their commentaries on Boethius and under the influence of Neoplatonism, twelfth century authors not only anticipate essential elements of thirteenth century metaphysics, they also make an original contribution to the history of metaphysics by attempting to integrate the theory of first principles, philosophical theology and ontology. This volume presents and examines the contributions of the twelfth century to metaphysics made by selected Jewish, Christian and Muslim authors of the Iberian Peninsula and Francia. Contributors include Matthias Lutz-Bachmann (Frankfurt am Main), Andreas Speer (Wurzburg), Charles Burnett (London), Alexander Fidora (Frankfurt am Main), Thomas Ricklin (Neuchatel), Yossef Schwartz (Jerusalem), Josep Udina (Barcelona), Jack C. Marler (St. Louis/USA), Gillian R. Evans (Cambridge), Andreas Niederberger (Frankfurt am Main) and Francoise Hudry (Paris).