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Oxidative Cross Coupling Reactions

Author: Aiwen Lei
Publisher: John Wiley & Sons
ISBN: 3527681000
Size: 29.53 MB
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The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.

Transition Metal Catalyzed Oxidative Cross Coupling Reactions

Author: Aiwen Lei
Publisher: Springer
ISBN: 3662581043
Size: 75.67 MB
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This book is a comprehensive text covering the research and development trends in the booming field of transition metal catalyzed oxidative cross-coupling reactions. Oxidative cross-coupling reaction is a new method to forming chemical bonds besides the traditional cross-coupling reactions. This book provides the answers to how this coupling reaction occurs and what its advantages are. The palladium, copper and iron catalyzed oxidative cross-coupling reactions as the main focuses of interest are described in detail. The oxidative cross-coupling reactions catalyzed by other metals and transition-metal-free oxidative coupling reactions are also introduced.This book provides a useful reference source for researchers and graduates in the field of transition metal catalyzed coupling reactions. It is also valuable to researchers working in pharmaceutical companies, fine organic chemical companies, and etc.

Copper Mediated Cross Coupling Reactions

Author: Gwilherm Evano
Publisher: John Wiley & Sons
ISBN: 1118690478
Size: 20.80 MB
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Providing comprehensive insight into the use of copper incross-coupling reactions, Copper-Mediated Cross-CouplingReactions provides a complete up-to-date collection of theavailable reactions and catalytic systems for the formation ofcarbon-heteroatom and carbon-carbon bonds. This essential referencecovers a broad scope of copper-mediated reactions, theirvariations, key advances, improvements, and an array of academicand industrial applications that have revolutionized the field oforganic synthesis. The text also discusses the mechanism ofthese transformations, the use of copper as cost-efficientalternative to palladium, as well as recently developed methods forconducting copper-mediated reactions with supported catalysts.

Science Of Synthesis Cross Coupling And Heck Type Reactions Vol 3

Publisher: Georg Thieme Verlag
ISBN: 313179111X
Size: 19.43 MB
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In "Science of Synthesis: Cross Coupling and Heck-Type Reactions", expert authors present and discuss the best and most reliable methods currently available for the formation of new carbon-carbon and carbon-heteroatom bonds using these reactions, highlighted with experimental procedures. The three volumes provide an extensive overview of the current state of the art in this field of central importance in modern chemistry, and are an invaluable resource for synthetic organic chemists. This volume covers the different classes of Heck-type reactions. It describes the developments in each area whilst critically evaluating the strengths and weaknesses of the different methods. Many of these newly developed Heck-type methods feature operationally convenient conditions, high catalytic efficiency, and high levels of chemical, regiochemical, and stereochemical control. // The content of this e-book was originally published in Dec. 2012.

C H Activation

Author: Jin-Quan Yu
Publisher: Springer
ISBN: 3642123562
Size: 79.40 MB
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Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds - Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C–H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation - Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages - Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds - Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C–H to C–N Bonds

Iodine Chemistry And Applications

Author: Tatsuo Kaiho
Publisher: John Wiley & Sons
ISBN: 1118878655
Size: 30.60 MB
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This book comprehensively covers iodine, its chemistry, and itsrole in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodinechemistry with discussion on elemental aspects: characteristics,properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how tosynthesize complex compounds using iodine reagents orintermediates • Describes traditional and modern processingtechniques, such as starch, cupper, blowing out, and ion exchangeresin methods • Includes seven detailed sections devoted to theapplications of iodine: Characteristics, Production, Synthesis,Biological Applications, Industrial Applications, BioorganicChemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalentiodine-mediated cross coupling reactions, agrochemicals, dyesensitized solar cells, and therapeutic agents


Author: John A. Joule
Publisher: Springer
ISBN: 3319078240
Size: 76.99 MB
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The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

New Trends In Cross Coupling

Author: Thomas Colacot
Publisher: Royal Society of Chemistry
ISBN: 1849738963
Size: 32.64 MB
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Following on from its recognition in the 2010 Nobel Prize for Chemistry, contributors from across the globe present the latest cross-coupling trends in both academia and industry.

Metal Catalyzed Cross Coupling Reactions

Author: A. de Meijere
Size: 37.68 MB
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In this second, completely revised and enlarged edition, Francois Diederich is joined by Armin de Meijere in bringing together in two comprehensive volumes everything of importance related to C-C and C-N cross-coupling reactions. The range of applications covered extends from the synthesis of complex natural materials via supramolecular chemistry right up to materials science. Internationally renowned experts pass on to the reader the current level of knowledge, while critical analyses of the latest developments and applications allow users to quickly decide for themselves on which strategies are available for solving their synthesis problems. In particular the experimental guidelines for key reactions developed by the authors for the widest possible range of applications testify to the practical advantages this handbook offers every organic chemist.

A Theoretical Study Of Pd Catalyzed C C Cross Coupling Reactions

Author: Max García Melchor
Publisher: Springer Science & Business Media
ISBN: 3319014900
Size: 36.43 MB
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Find out how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions in Max Garcia Melchor's outstanding thesis. Garcia Melchor investigates one of the most significant and useful types of reactions in modern organic synthesis; the Pd-cross coupling reaction. Due to its versatility, broad scope and selectivity under mild conditions, this type of reaction can now be applied in fields as diverse as the agrochemical and pharmaceutical industry. Garcia Melchor studies the reaction intermediates and transition states involved in the Negishi, the copper-free Sonogashira and the asymmetric version of Suzuki-Miyaura coupling. He also characterizes and provides a detailed picture of the associated reaction mechanisms. The author has won numerous prizes for this work which has led to over eight publications in internationally renowned journals.