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Transition Metal Organometallic Chemistry

Author: Francois Mathey
Publisher: Springer Science & Business Media
ISBN: 9814451096
Size: 64.97 MB
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This book serves as a concise guide to essential topics in Transition Metal Organometallic Chemistry for senior undergraduate and graduate students; it blends qualitative theoretical approach with experimental description of the facts. Its content emphasizes on the orbital description of M-L bonds; the electronic structures of the main types of organometallic complexes (ML2 to ML6); main types of organometallic reactions; organometallic compound synthesis, analytical characterization and the reactivity and lastly the applications of transition metals in homogeneous catalysis.

Metal Molecular Assembly For Functional Materials

Author: Yutaka Matsuo
Publisher: Springer Science & Business Media
ISBN: 4431543708
Size: 62.82 MB
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This book focuses on modern coordination chemistry, covering porous coordination polymers, metalloproteins, metallopeptides, nanoclusters, nanocapsules, aligned polymers, and fullerenes. As well, it deals with applications to electronic devices and surface characterization. These wide-ranging topics are integrally described from the perspectives of dimensionality (one-, two-, and three-dimension), new materials design, synthesis, molecular assembly, function and application. The nine chapters making up this book have been authored by scientists who are at the cutting edge of research in this particular field. The level is appropriate for graduate students, post-doc researchers, and new faculty members whose aim is to become familiar with modern coordination chemistry from its basics to applications.

Sulfur Dioxide Insertion Reactions For Organic Synthesis

Author: Danqing Zheng
Publisher: Springer
ISBN: 9811042020
Size: 60.80 MB
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This brief summarizes the most commonly used sulfur dioxide surrogates and also shows the diverse reactivities to highlight the advances made in the development of synthetic methods through the insertion of sulfur dioxide. Depending on the nature of the transformation, these reactions are classified into four types: (i) pericyclic reactions; (ii) nucleophilic addition with organometallic reagents; (iii) transition metal catalysis; and (iv) free radical reactions. Highlighting recent advances in the insertion of sulfur dioxide, providing detailed descriptions of the experimental procedures for these valuable reactions, and discussing the remaining challenges in this field, the brief offers an appealing and highly useful guide for a wide readership in organic chemistry and medicinal chemistry from both academia and industry.

The Organometallic Chemistry Of The Transition Metals

Author: Robert H. Crabtree
Publisher: John Wiley & Sons
ISBN: 0470257628
Size: 61.73 MB
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"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and?detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers?in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.

Chemical Transformations Of Vinylidenecyclopropanes

Author: Lixiong Shao
Publisher: Springer Science & Business Media
ISBN: 3642275737
Size: 69.19 MB
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Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.

Sustainable C Sp3 H Bond Functionalization

Author: Jin Xie
Publisher: Springer
ISBN: 3662494965
Size: 12.36 MB
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This book highlights major achievements made in the last five years concerning sustainable C(sp3)-H bond functionalization and offers a promising and emerging tool-kit for organic synthesis. The book is divided into three chapters demonstrating key advances in C(sp3)-H bond functionalization. Chapter 1 reviews transition-metal-catalyzed C(sp3)-H bond functionalization using different directing groups, while Chapter 2 addresses the new methods of transition-metal-catalyzed and metal-free C(sp3)-H bond functionalization without directing groups, in addition to briefly highlighting redox-neutral C(sp3)-H bond functionalization. In closing, Chapter 3 examines visible-light photoredox catalysis, an emerging and highly sustainable C(sp3)-H bond functionalization strategy. The book offers an intriguing and useful reference guide for a broad readership working and/or interested in the fields of organic, organometallic, and green chemistry.

Organometallic Chemistry

Author: M. Green
Publisher: Royal Society of Chemistry
ISBN: 9780854043385
Size: 58.91 MB
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This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Up From Generality

Author: Jay A. Labinger
Publisher: Springer Science & Business Media
ISBN: 3642401201
Size: 66.51 MB
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In this brief, renowned inorganic chemist Jay Labinger tracks the development of his field from a forgotten specialism to the establishment of an independent, intellectually viable discipline. Inorganic chemistry, with a negation in its very name, was long regarded as that which was left behind when organic and physical chemistry emerged as specialist fields in the 19th century. Only by the middle of the 20th century had it begun to gain its current stature of equality to that of the other main branches of chemistry. The author discusses the evidence for this transition, both quantitative and anecdotal and includes consideration of the roles of local and personal factors, with particular focus on Caltech as an illustrative example. This brief is of interest both to historians of science and inorganic chemists who would like to find out how their field began.

Transformation Of Carbon Dioxide To Formic Acid And Methanol

Author: Wan-Hui Wang
Publisher: Springer
ISBN: 9811032505
Size: 70.48 MB
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This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.

Milestones In Microwave Chemistry

Author: György Keglevich
Publisher: Springer
ISBN: 3319306324
Size: 56.21 MB
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This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decades, one driven by the advent of increasingly sophisticated professional MW reactors in place of the kitchen MW ovens used in earlier years. A major part of the book shows how substitutions, esterifications, amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations, cyclizations, C–C couplings and the modification of heterocycles can be performed advantageously under MW irradiation, as the reaction times are shorter, while the selectivity and yields are higher; it also explains why in most cases, the reactions can be performed under solvent-free conditions. MW irradiation within the sphere of organophosphorus chemistry is showcased and typical reactions, such as the direct derivatization of phosphinic acids, alkylating esterifications, Diels–Alder reactions, the inverse Wittig-type reaction, fragmentations, the Arbuzov reaction, the synthesis of α-hydroxyphosphonates and α-aminophosphonates (the Kabachnik–Fields condensation), deoxygenations and P–C coupling reactions are described under MW conditions. In closing, the advantages of MW chemistry such as faster reactions and the possibility of simplifying the catalytic systems are addressed.